Tag: Radical Photochemical Reactions
Organic-dye CDC method adds fluoronitromethane to tetrahydroisoquinolines
Organocatalytic cross-dehydrogenative coupling of tetrahydroisoquinolines with fluoronitromethane using Rose Bengal and green LED irradiation for sustainable fluorinated compound synthesis.
Photocatalysis enabled synthesis of trifluoromethyl amidines and imidates
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in ChemistryPhotocatalytic metal-free synthesis of α-trifluoromethyl amidines and imidates using isocyanides and trifluoroacetylsilanes, with mechanistic insights from DFT studies.
Pentafluoroethylation of styrenes expanded by a sulfoximine reagent
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in ChemistrySynthesis and photocatalytic application of pentafluoroethyl sulfoximine for difunctionalization of styrenes via concurrent C-C and C-heteroatom bond formation under mild conditions.
Photoredox method enables deoxytrifluoromethoxylation of phenols
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in ChemistryPhotoredox-catalyzed deoxytrifluoromethoxylation installs OCF3 groups on phenols via in situ difluorophosgene generation and aryl carbonofluoridate activation.
