Tag: Asymmetric Synthesis and Catalysis
Oxoammonium catalysis enables enantioselective desymmetrization of meso-pyrrolidines
Oxoammonium-catalyzed desymmetrization of meso-pyrrolidines via enantioselective hydride transfer with over 90% ee, featuring mechanistic insights from isolated intermediates.
Chiral carbon-bonding donors showed asymmetric induction
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Carbon-bonding donors induce asymmetric induction via noncovalent interaction, demonstrated through oxa-Pictet-Spengler cyclization with oxocarbenium intermediates.
