Radical Photochemical Reactions
External reference: https://openalex.org/T10701
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Organic-dye CDC method adds fluoronitromethane to tetrahydroisoquinolines Organocatalytic cross-dehydrogenative coupling of tetrahydroisoquinolines with fluoronitromethane using Rose Bengal and green LED irradiation for sustainable fluorinated compound synthesis.
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Photocatalysis enabled synthesis of trifluoromethyl amidines and imidates Photocatalytic metal-free synthesis of α-trifluoromethyl amidines and imidates using isocyanides and trifluoroacetylsilanes, with mechanistic insights from DFT studies.
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Indole-based synthesis yields α-perfluoroalkylamino derivatives Novel sequential perfluoroalkylation and defluoroamination of indoles via sulfinate-derived radicals and HMDS-mediated C-F cleavage, yielding α-trifluoromethylated amines in up to 80% yield.
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Pentafluoroethylation of styrenes expanded by a sulfoximine reagent Synthesis and photocatalytic application of pentafluoroethyl sulfoximine for difunctionalization of styrenes via concurrent C-C and C-heteroatom bond formation under mild conditions.
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Photoredox method enables deoxytrifluoromethoxylation of phenols Photoredox-catalyzed deoxytrifluoromethoxylation installs OCF3 groups on phenols via in situ difluorophosgene generation and aryl carbonofluoridate activation.