Organometallic Complex Synthesis and Catalysis
External reference: https://openalex.org/T10092
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Aryl Halide Carboxylation via Decarboxylative Metal–Halogen Exchange Novel decarboxylative metal-halogen exchange mechanism enables mild carboxylation of aryl halides using bench-stable potassium carboxylate salts without pressurized equipment or organometallic.
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Valence bond representations with +ve charges on adjacent atoms? An odd titanium complex analysed. Computational analysis of titanium complexes reveals that adjacent positively charged nitrogen atoms form stable bonds with unusually low interaction energies.
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Cyclometalated platinum products depend on the halogen in the ligand Study of cyclometalated platinum compounds formed via competing C-H and C-X bond activation pathways, with mechanistic insights from computational and spectroscopic analysis.
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Additive covalent radii fitted for near-sixfold metal bonds Additive covalent radii for sixfold metal-metal bonded dimers across transition metals and actinides with 12 valence electrons in (1σ)²(2σ)²π⁴δ⁴ configuration.
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New fused NiII porphyrin dimers were synthesized Synthesis of fused-azepine- and 1H-azocine-bridged NiII porphyrin dimers via Pictet-Spengler cyclization and oxidative transformations, yielding NIR-absorbing and fluorescent complexes.