Focal Interest
Focal Interest

Group (periodic table)

  1. Additive covalent radii fitted for near-sixfold metal bonds
    Additive covalent radii for sixfold metal-metal bonded dimers across transition metals and actinides with 12 valence electrons in (1σ)²(2σ)²π⁴δ⁴ configuration.
  2. Stereochemical assignment of trifluoroacetamides using NMR signals
    Stereochemical assignment of N,N-dialkyl trifluoroacetamides using integrated analysis of through-space 1H···19F spin-spin couplings and aromatic solvent-induced shifts in 1H-NMR spectroscopy.