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Light-triggered CO2 binding enables CO production in a cerium MOF
Cerium metal-organic framework with amino linkers achieves 100% selective photoreduction of CO2 to CO at 126 μmol·g-1·h-1 via transient Ce(III) sites and reversible binding.
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Tetraethynyl DOTs show π-stacking and n-type semiconductor behavior
Tetraethynyl dioxotriangulene derivatives synthesized via C–O activation demonstrate n-type semiconductor properties through π-stacking and radical anion stabilization in field-effect transistors.
