Coordination Chemistry and Organometallics

External reference: https://openalex.org/T12228

  1. Thiolate-mediated cyclization yields 2-quinolones from aminocinnamic acids
    Thiolate-mediated cyclization protocol for synthesis of 2-quinolones and 2-aza-quinolones from aminocinnamic acid derivatives with broad substrate scope and gram-scale scalability.
  2. 2-Lithiomethylindoles enable diverse 2-functionalized indoles
    Optimized α-lithiation protocol for 1,2-dimethylindoles enables efficient C2-functionalization via diverse electrophile trapping in deep eutectic solvents under air-tolerant conditions.
  3. Low-temperature lithium-metal batteries improved by hierarchical solvation
    Hierarchical solvating electrolyte enables high-performance lithium-metal batteries at extreme low temperatures through molecular engineering of solvation sheaths and solid electrolyte interphase.
  4. In Situ Organoselenization for Ultrastable Li−Se Batteries
    In situ organoselenization strategy converts selenium into organic selenide forms to prevent polyselenide shuttle in lithium-selenium batteries, achieving 92.87% capacity retention after 1300 cycles.
  5. Phenanthrenone-derived ketone is more electrophilic than acenaphthenone-derived ketone
    Kinetic and computational quantification of electrophilicity for phenanthrenone‑ and acenaphthenone‑derived α,β‑unsaturated ketones: Mayr E parameters, transition‑state analysis, and.
  6. Frozen organic electrolyte conducts lithium ions
    Demonstration that frozen ethylene carbonate with 0.2 m LiTFSI conducts Li+ via solid-state hopping (≈0.64 mS/cm, t+≈0.8), enabling liquid-level cell capacity and Li2O-rich SEI with extended.